• 文献标题:   In situ formation of Co3O4 nanocrystals embedded in laser-induced graphene foam for high-energy flexible micro-supercapacitors
  • 文献类型:   Article
  • 作  者:   DING XH, LIU RL, ZHAO JY, HU JP, WU JJ, ZHANG C, LIN J
  • 作者关键词:  
  • 出版物名称:   DALTON TRANSACTIONS
  • ISSN:   1477-9226 EI 1477-9234
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1039/d1dt03848f EA JAN 2022
  • 出版年:   2022

▎ 摘  要

The cost-effective synthesis of flexible energy storage devices with high energy and power densities is a challenge in wearable electronics. Here, we report a facile, efficient, and scalable approach for preparing three-dimensional (3D) laser-induced graphene foam (Co3O4@LIG) embedded with porous Co3O4 nanocrystals using a CO2 infrared laser. The in situ formed Co3O4@LIG nanocomposites directly serve as active materials, current collectors, and the conductive substrate for micro-supercapacitors (MSCs). Benefiting from rational structural features, the MSC based on Co3O4@LIG nanocomposites (Co3O4@LIG-MSC) with an interdigitated electrode configuration exhibits excellent electrochemical performance, including a high specific capacitance (143.5 F g(-1)), excellent rate capability, high energy density (19.9 W h kg(-1) at a power density of 0.5 W kg(-1)), and remarkable power density (15.0 W kg(-1) at an energy density of 15.8 W h kg(-1)). Furthermore, the device possesses good stability under different bending diameters and cycling stability. Such a highly integrated flexible MSC with high energy and power densities made by a directly laser scribing strategy has some potential for the fabrication of wearable energy storage devices.