• 文献标题:   Hierarchical nanocomposites of polyaniline scales coated on graphene oxide sheets for enhanced supercapacitors
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   LI M, YIN WC, HAN XL, CHANG XQ
  • 作者关键词:   panigo nanocomposite, cumene hydroperoxideiron dichloride, supercapacitor, specific capacitance, rate capacity
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Qilu Univ Technol
  • 被引频次:   7
  • DOI:   10.1007/s10008-016-3202-y
  • 出版年:   2016

▎ 摘  要

The homogeneous polyaniline-graphene oxide (PANI-GO) nanocomposites were facilely assembled with a redox system in which cumene hydroperoxide (CHP) and iron dichloride (FeCl2) acted as oxidant and reductant, respectively. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images showed that PANI scales coated uniformly on the surface of GO sheets owing to the synergistic effect between the PANI and GO. The obtained PANI-GO nanocomposites exhibited improved electrochemical performance as an electrode material for supercapacitors compared with the pure PANI. The specific capacitance of the PANI-GO nanocomposites was high up to 308.3 F g(-1), much higher than that of the pure PANI with specific capacitance of 150 F g(-1) at a current density of 1 A g(-1) in 2 M H2SO4 electrolyte. The Raman and XPS results illustrated that enhanced electrochemical performance might be attributed to the pi-pi conjugation between the PANI and GO sheets.