▎ 摘　　要

Ultrafast carrier response of perovskite/MoO3/graphene heterostructure was investigated by optical-pump terahertz (THz) probe spectroscopy. The high work function of MoO3 changes the tunable graphene Fermi level via hole doping. Compared with monolayer graphene, it generates a more negative photoconductivity and enables ultra-fast THz functional manipulation. The subsequent THz signal decrease is related to hot-carrier cooling and the carrier concentration contributed by the CH3NH3PbI3 layer. The charge transfer and recombination reduce the positive conductance of the hybrid structure relative to that of neat CH3NH3PbI3.