▎ 摘　　要

Alkali lignins and its degradation products in the soda papermaking black liquor (SPBL) are renewable resource with the highest natural carbon content. In this work we convert SPBL into the highperformance carbon-based nanocomposite anodes. The unique functional groups of lignin biomass induce spontaneous formation of graphene-like carbon sheet (GCS) in-situ doped SiC/S. The lamellar GCS/Fe3O4 nanocomposite (GCS/FO-NC) is facilely prepared via one-step in-situ thermo-chemical method at 700 degrees C, in which donut shaped Fe3O4 nanoparticles with superlattices and inner surface are homogeneously embedded in the interlayer of GCS and are also anchored on its surface. The GCS/FO-NC anode exhibits a ultrahigh first discharge specific capacity of 3829 mAh g(-1) at 50 mA g(-1) in a coin-type Li ion battery, which is more than 4 times the theoretical capacity (924 mAh g(-1)) of Fe3O4 and 5 times that of the graphene anode (744 mAh. g(-1)). Even at a high current density (1000 mA g(-1)), it still exhibits a high reversible capacity (750 mAh g(-1)) after 1400 discharge/charge cycles. More importantly, the removal efficiency of chemical oxygen demand of SPBL is up to 83.4% during the synthesis process, which reduce its load to environment and synthetic cost of carbon-based nanocomposite anodes. (C) 2017 Elsevier Ltd. All rights reserved.