• 文献标题:   Liquid-phase oxidation of toluene to benzaldehyde with molecular oxygen catalyzed by copper nanoparticles supported on graphene
  • 文献类型:   Article
  • 作  者:   SONG GL, FENG L, XU J, ZHU HJ
  • 作者关键词:   copper nanoparticle, graphene, toluene oxidation
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Nanjing Tech Univ
  • 被引频次:   2
  • DOI:   10.1007/s11164-018-3404-2
  • 出版年:   2018

▎ 摘  要

Highly-dispersed copper nanoparticles (Cu NPs) were fabricated on the surface of reduced graphene oxide via direct hydrazine hydrate reduction of Cu2+ in aqueous solution. Scanning electron microscope and transmission electron microscope images show that the Cu NPs are distributed on the surface of graphene nanosheets, and the average particle size was about 40 nm. The Cu NPs supported on graphene have high reaction activity for the oxidation of toluene to corresponding benzaldehyde. It was found that the selectivity reached 66.5% and the conversion of toluene reached 11.5%.