• 文献标题:   Nitrogen-Doped Graphene as Electrode Material with Enhanced Energy Density for Next-Generation Supercapacitor Application
  • 文献类型:   Article
  • 作  者:   KESAVAN T, ASWATHY R, RAJ IA, KUMAR TP, RAGUPATHY P
  • 作者关键词:  
  • 出版物名称:   ECS JOURNAL OF SOLID STATE SCIENCE TECHNOLOGY
  • ISSN:   2162-8769
  • 通讯作者地址:   Cent Electrochem Res Inst
  • 被引频次:   8
  • DOI:   10.1149/2.0281512jss
  • 出版年:   2015

▎ 摘  要

Nitrogen-doped graphene (NDG), synthesized from graphene oxide by a hydrothermal process, was used to construct a non-aqueous symmetric supercapacitor. The electrochemical performance of NDG was evaluated using cyclic voltammetry, galvanostatic charge-discharge cycling and impedance analysis in a symmetrical hybrid supercapacitor cell with 1 M tetraethyl ammonium tetrafluoroborate in acetonitrile as the electrolyte. The specific capacitance of NDG is 103 F g(-1) at a current density of 0.5 mA cm(-2). The NDG product exhibits a remarkably high energy density of 97 Wh kg(-1), which is double that of conventional lead-acid batteries. The superior capacitive behavior has also been compared with a few representative capacitor materials. (C) 2015 The Electrochemical Society. All rights reserved.