• 文献标题:   Intercalated SiOC/graphene composites as anode material for li-ion batteries
  • 文献类型:   Article
  • 作  者:   REN YR, YANG B, HUANG XB, CHU FQ, QIU JH, DING JN
  • 作者关键词:   anode material, insitu reaction, sioc/gns
  • 出版物名称:   SOLID STATE IONICS
  • ISSN:   0167-2738 EI 1872-7689
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   6
  • DOI:   10.1016/j.ssi.2015.06.020
  • 出版年:   2015

▎ 摘  要

Intercalated SiOC/graphene composites had been prepared by thermal reduction of TTCS/GO mixture, which was fabricated by dispersing GO into TTCS. Transmission electron microscopy (TEM) showed that SiOC nanoparticles were well encapsulated in a graphene matrix. The 10SiOC/graphene anode maintained a reversible capacity of 582 mAh/g after 90 cycles and had an initial coulombic efficiency of 63%. The excellent cycling stability is attributed to the fact that the SiOC/graphene composite can accommodate large volume change of SiOC and maintain good electronic contact. These results indicate that SiOC/graphene is an excellent anode material and has promising prospects in lithium ion batteries (LIBS) applications. (C) 2015 Elsevier B.V. All rights reserved.