• 文献标题:   Surface Modification of Nanocrystalline LiMn2O4 Using Graphene Oxide Flakes
  • 文献类型:   Article
  • 作  者:   MICHALSKA M, BUCHBERGER DA, JASINSKI JB, THAPA AK, JAIN A
  • 作者关键词:   lithium manganese oxide, limn2o4, graphene oxide, cathode material, lithium ion battery
  • 出版物名称:   MATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.3390/ma14154134
  • 出版年:   2021

▎ 摘  要

In this work, a facile, wet chemical synthesis was utilized to achieve a series of lithium manganese oxide (LiMn2O4, (LMO) with 1-5%wt. graphene oxide (GO) composites. The average crystallite sizes estimated by the Rietveld method of LMO/GO nanocomposites were in the range of 18-27 nm. The electrochemical performance was studied using CR2013 coin-type cell batteries prepared from pristine LMO material and LMO modified with 5%wt. GO. Synthesized materials were tested as positive electrodes for Li-ion batteries in the voltage range between 3.0 and 4.3 V at room temperature. The specific discharge capacity after 100 cycles for LMO and LMO/5%wt. GO were 84 and 83 mAh g(-1), respectively. The LMO material modified with 5%wt. of graphene oxide flakes retained more than 91% of its initial specific capacity, as compared with the 86% of pristine LMO material.