• 文献标题:   Exfoliated Pd decorated graphene oxide nanosheets (Pd-NP-GO/P123): Non-toxic, ligandless and recyclable in greener Hiyama cross-coupling reaction
  • 文献类型:   Article
  • 作  者:   ROSTAMNIA S, ZEYNIZADEH B, DOUSTKHAH E, HOSSEINI HG
  • 作者关键词:   graphene oxide, exfoliated pdgo, surfactant, hiyama reaction, crosscoupling
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Univ Maragheh
  • 被引频次:   26
  • DOI:   10.1016/j.jcis.2015.03.040
  • 出版年:   2015

▎ 摘  要

Graphene oxide nanosheets were applied as a support for Pd nanoparticles in Hiyama reaction of various aryl halides and triethoxyphenylsilane to generate biaryl derivatives in aqueous conditions. Addition of surfactant during the catalysis caused a significant increase in yields of products through well-exfoliation of Pd-NP-GO. Among various studied surfactants, P123 showed superior activity rather to other surfactants, SDS and CTAB. This heterogeneous catalytic system has attained the advantages of being non-toxic, available, recyclable, ligand-free, and compatible to reaction medium. (C) 2015 Elsevier Inc. All rights reserved.