• 文献标题:   SnO2 quantum dots @ 3D sulfur-doped reduced graphene oxides as active and durable anode for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   WU K, SHI BW, QI LY, MI YY, ZHAO BL, YANG CK, WANG Q, TANG H, LU J, LIU W, ZHOU HH
  • 作者关键词:   sno2 quantum dot, anode material, sulfurdoping, graphene, lithium ion battery
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Peking Univ
  • 被引频次:   9
  • DOI:   10.1016/j.electacta.2018.09.086
  • 出版年:   2018

▎ 摘  要

SnO2 has attracted growing attention as a promising anode material for next generation of Lithium ion batteries because of its high theoretical capacity (1494 mAh g(-1)) and low working potential. However, the severe volume change during cycling remains one of the great challenges for its practical application. To overcome the obstacle, we propose to utilize the SnO2 quantum dots loaded on the sulfur-doped reduced graphene oxides by one-pot synthesis. The SnO2 quantum dots are uniformly dispersed on the sulfur-doped reduced graphene oxides and retain their tiny sizes during the electrochemical reaction, thus alleviate the volume expansion. Meanwhile, the sulfur-doped reduced graphene oxides introduces many defects and can benefit charge transfer and lithium ion diffusion in the electrode. With the synergetic effect between SnO2 quantum dots and sulfur-doped reduced graphene oxides, the composite anode material can deliver a specific capacity of 897 mAh g(-1) at 100 mA g(-1) and maintain 88% of original capacity after over 500 cycles at 500 mA g(-1), featuring large lithium ion storage capacity and high stability. (C) 2018 Elsevier Ltd. All rights reserved.