• 文献标题:   Amperometric L-cysteine sensor based on a carbon paste electrode modified with Y2O3 nanoparticles supported on nitrogen-doped reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   YANG SL, LI G, WANG YY, WANG GF, QU LB
  • 作者关键词:   electroanalysi, cyclic voltammetry, chronoamperometry, xray diffraction, xray photoelectron spectroscopy, field emission scanning electronmicroscopy, tem, ftir
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Anyang Normal Univ
  • 被引频次:   25
  • DOI:   10.1007/s00604-015-1737-8
  • 出版年:   2016

▎ 摘  要

We describe an electrochemical sensor for L-cysteine that is based on the use of Y2O3 nanoparticles (Y2O3-NPs) supported on nitrogen-doped reduced graphene oxide (N-rGO). The material was characterized by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and electrochemical methods. Deposited on a carbon paste electrode, the material displays a strongly oxidation peak for L-cysteine at pH 7.0 (compared to an unmodified electrode). The current, measured at a potential 0.7 V (vs. Ag/AgCl), increases linearly in the 1.3 to 720 mu M L-cysteine concentration range, and the detection limit is 0.8 mu M. The sensor was successfully applied to the determination L-cysteine in spiked syrup.