• 文献标题:   Superior electrochemical properties of manganese dioxide/reduced graphene oxide nanocomposites as anode materials for high-performance lithium ion batteries
  • 文献类型:   Article
  • 作  者:   LEE SW, LEE CW, YOON SB, KIM MS, JEONG JH, NAM KW, ROH KC, KIM KB
  • 作者关键词:   lithium ion batterie, manganese dioxide, reduced graphene oxide, nanocomposite, highperformance anode material, energy efficiency
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Yonsei Univ
  • 被引频次:   35
  • DOI:   10.1016/j.jpowsour.2016.02.049
  • 出版年:   2016

▎ 摘  要

MnO2/reduced graphene oxide (rGO) nanocomposites were synthesized via a simple solution method at room temperature for use in Li-ion batteries. Owing to the mesoporous features as well as the high electrical conductivity of rGO, the overall electronic and ionic conductivities of the nanocomposite were increased, resulting in improved electrochemical properties in terms of specific capacity, rate capability, and cyclability. In particular, as-prepared nanocomposites showed 222 and 115 mAh g(-1) at a current density of as high as 5 and 10 A g(-1), and the specific capacitance was well maintained after 400 cycles. In addition, MnO2, via composite formation with rGO, permitted the additional conversion reaction between MnO and Mn3O4, resulting in the reduction of the initial irreversible capacity despite the high first discharge capacity caused by the large specific surface area. (C) 2016 Elsevier B.V. All rights reserved.