• 文献标题:   Decontamination of Sr(II) on Magnetic Polyaniline/Graphene Oxide Composites: Evidence from Experimental, Spectroscopic, and Modeling Investigation
  • 文献类型:   Article
  • 作  者:   HU BW, QU MQ, HU QY, SUN YB, SHENG GD, HU J, MA JY
  • 作者关键词:   sr ii, magnetic graphene oxide, polyaniline, exafs, modeling
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Shaoxing Univ
  • 被引频次:   35
  • DOI:   10.1021/acssuschemeng.7b01126
  • 出版年:   2017

▎ 摘  要

The interaction of Sr(II) on magnetic polyaniline/graphene oxide (PANI/GO) composites was elucidated by batch, EXAFS, and surface complexation modeling techniques. The batch experiments showed that decreased uptake of Sr(II) on magnetic PANI/GO composites was observed with increasing ionic strength at pH <5.0, whereas no effect of ionic strength on Sr(II) uptake was shown at pH >5.0. The maximum uptake capacity of magnetic PANI/GO composites derived from the Langmuir model at pH 3.0 and 293 K was 37.17 mg/g. The outer sphere surface complexation controlled the uptake of Sr(II) on magnetic PANI/GO composites at pH 3.0 due to the similarity to the EXAFS spectra of Sr2+ in aqueous solutions, but the Sr(II) uptake at pH 7.0 was inner sphere complexation owing to the occurrence of the Sr-C shell. According to the analysis of surface complexation modeling, uptake of Sr(II) on magnetic PANI/GO composites was well simulated using a diffuse layer model with an outer-sphere complex (SOHSr2+ species) and two inner sphere complexes (i.e., (SO)(2)Sr(OH)(-) and SOSr+ species). These findings are crucial for the potential application of magnetic nanomaterials as a promising candidate for the uptake of radionuclides for environmental remediation.