• 文献标题:   Nitrogen-doped three-dimensional graphene-supported platinum catalysts for polymer electrolyte membrane fuel cells application
  • 文献类型:   Article
  • 作  者:   CHU FQ, LI XX, YUAN WS, ZHU HH, QIN Y, ZHANG S, YUAN NY, LIN BC, DING JN
  • 作者关键词:   catalyst, carbon material, fuel cell, graphene, nanoparticle
  • 出版物名称:   FUNCTIONAL MATERIALS LETTERS
  • ISSN:   1793-6047 EI 1793-7213
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   0
  • DOI:   10.1142/S1793604718500157
  • 出版年:   2018

▎ 摘  要

Catalysts are a key component of polymer electrolyte membrane fuel cells (PEMFCs). In this work, nitrogen-doped three-dimensional graphene-supported platinum (Pt-3DNG) catalysts are successfully prepared and characterized. SEM and TEM images show the Pt nanoparticles are uniformly dispersed in the sheets of nitrogen-doped 3DNG. Compared with that of the commercial Pt/C catalysts, Pt-3DNG show much better oxygen reduction reaction (ORR) activity and cycling stability, and the reduction in limit current density after 1000 cycles is only about 1.6% for the Pt-3DNG catalysts, whereas 7.2% for the commercial Pt/C catalysts. The single cell using Pt-3DNG catalysts in both the anode and the cathode show a higher peak power density (21.47mW cm(-2)) than that using commercial Pt/C catalysts (20.17mW cm(-2)) under the same conditions. These properties make this type of catalyst suitable for the application in PEMFCs.