• 文献标题:   Highly Efficient Visible Light Mediated Azo Dye Degradation Through Barium Titanate Decorated Reduced Graphene Oxide Sheets
  • 文献类型:   Article
  • 作  者:   RASTOGI M, KUSHWAHA HS, VAISH R
  • 作者关键词:   bariumtitanatereduced graphene oxide composite, solar photocatalysi, dye degradation, water treatment
  • 出版物名称:   ELECTRONIC MATERIALS LETTERS
  • ISSN:   1738-8090 EI 2093-6788
  • 通讯作者地址:   Indian Inst Technol Mandi
  • 被引频次:   12
  • DOI:   10.1007/s13391-015-5274-8
  • 出版年:   2016

▎ 摘  要

This study investigates BaTiO3 decorated reduced graphene oxide sheets as a potential visible light active catalyst for dye degradation (Rhodamine B). The composites were prepared through conventional hydrothermal synthesis technique using hydrazine as a reducing agent. A number of techniques have been employed to affirm the morphology, composition and photocatalytic properties of the composites; these include UV-visible spectrophotoscopy that assisted in quantifying the concentration difference of Rhodamine B. The phase homogeneity of the composites was examined through x-ray powder diffraction (XRD) and high resolution transmission electron microscopy (HRTEM) was employed to confirm the orientation of the BaTiO3 particles over the reduced graphene oxide sheets. Photoluminescence (PL) emission spectra assisted in determining the surface structure and excited state of the catalyst. Fourier transformed-infrared (FTIR) spectra investigated the vibrations and adsorption peak of the composites, thereby ascertaining the formation of reduced graphene oxide. In addition, diffuse reflectance spectroscopy (DRS) demonstrated an enhanced absorption in the visible region. The experimental investigations revealed that graphene oxide acted as charge collector and simultaneously facilitated surface adsorption and photo-sensitization. It could be deduced that BaTiO3-reduced graphene oxide composites are of significant interest the field of water purification through solar photocatalysis.