• 文献标题:   Doping Dependence of the Raman Spectrum of Defected Graphene
  • 文献类型:   Article
  • 作  者:   BRUNA M, OTT AK, IJAS M, YOON D, SASSI U, FERRARI AC
  • 作者关键词:   graphene, raman spectroscopy, defect
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Cambridge
  • 被引频次:   147
  • DOI:   10.1021/nn502676g
  • 出版年:   2014

▎ 摘  要

We investigate the evolution of the Raman spectrum of defected graphene as a function of doping. Polymer electrolyte gating allows us to move the Fermi level up to 0.7 eV, as directly monitored by in situ Hall-effect measurements. For a given number of defects, we find that the intensities of the D and D' peaks decrease with increasing doping. We assign this to an increased total scattering rate of the photoexcited electrons and holes, due to the doping-dependent strength of electron-electron scattering. We present a general relation between D peak intensity and defects valid for any doping level.