• 文献标题:   Sensitive and Selective Sensing of Hydrogen Peroxide with Iron-Tetrasulfophthalocyanine-Graphene-Nafion Modified Screen-Printed Electrode
  • 文献类型:   Article
  • 作  者:   ZHU MF, LI N, YE JS
  • 作者关键词:   irontetrasulfophthalocyanine, graphene, screenprinted electrode, amperometric sensor, h2o2
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   14
  • DOI:   10.1002/elan.201200039
  • 出版年:   2012

▎ 摘  要

We developed a novel iron-tetrasulfophthalocyanine-graphene-Nafion (FeTSPc-GR-Nafion) modified screen-printed electrode to determine hydrogen peroxide (H2O2) with high sensitivity and selectivity. The nanocomposite film (FeTSPc-GR-Nafion) exhibits an excellent electrocatalytic activity towards oxidation of H2O2 at a potential of +0.35 V in the absence of enzyme. A comparative study reveals that the FeTSPc-GR complexes play a dual amplification role. Amperometric experiment indicates that the sensors possess good sensitivity and selectivity, with a linear range from 2.0X10-7 M to 5.0X10-3 M and a detection limit of 8.0X10-8 M. This sensor has been successfully used to develop the glucose biosensor and has also been applied to determine H2O2 in sterile water.