• 文献标题:   Supercapacitors Based on Graphene-Supported Iron Nanosheets as Negative Electrode Materials
  • 文献类型:   Article
  • 作  者:   LONG CL, WEI T, YAN J, JIANG LL, FAN ZJ
  • 作者关键词:   supercapacitor, graphene, iron nanosheet, ultrahigh energy density
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Harbin Engn Univ
  • 被引频次:   130
  • DOI:   10.1021/nn405192s
  • 出版年:   2013

▎ 摘  要

We report a facile strategy to prepare iron nanosheets directly grown on graphene sheets nanocomposite (C-PGF) through the carbonization of iron ions adsorbed onto polyaniline nanosheet/graphene oxide hybrid material. Because of the synergistic effect of iron nanosheets and graphene sheets, the as-obtained C-PGF exhibits an ultrahigh capacitance of ca. 720 F g(-1) in 6 M KOH aqueous solution. Additionally, the assembled asymmetric supercapacitor (C-PGF//Ni(OH)(2)/CNTs) delivers a remarkable high power density and a noticeable ultrahigh energy density of ca. 140 Wh kg(-1) (based on the total mass of active materials) and an acceptable cycling performance of 78% retention after 2000 cycles. Therefore, the designed supercapacitors with high energy density, comparable to rechargeable lithium-ion batteries (LIBs), offer an important guideline for future design of advanced next-generation supercapacitors for both industrial and consumer applications.