• 文献标题:   Effects of Graphene/Silver Nanocomposite on the Microstructure of Amorphous Mg-based Hydride
  • 文献类型:   Article
  • 作  者:   HUANG LJ, WANG YX, TANG JG, WANG Y, LIU JX, JIAO JQ, WANG W
  • 作者关键词:   electrode alloy, graphene coating, electrochemical property, surface modification
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   0
  • DOI:   10.20964/2016.12.10
  • 出版年:   2016

▎ 摘  要

The influence of a graphene/silver (G/A) nanocomposite coating layer on the microstructural evolution and surface oxidation of a Mg-Ni-La hydride is investigated systematically by XRD, SEM, EDS and HRTEM in detail. SEM and EDS reveal that the existence of the G/A composite prevents the electrode from pulverizing and oxidizing. The oxygen content in the surface of the electrode is reduced from 21.26% to 9.83% after 50 cycles for a Mg-Ni-La electrode with 0.2 mass fraction of G/A. HRTEM shows that the amorphous electrodes with no G/A coating are almost all crystallized, and that the stable Mg2NiH4, alpha-Mg, MgH2 and LaH2 phases are present with grain sizes as large as 100-120 nm after 50 cycles of charging/discharging. The G/A coating reduces the corrosion and oxidation of the electrode alloy and provides both a pathway for hydrogen diffusion and active sites for the redox reaction of hydrogen. All these factors generate a significant enhancement of the discharge capacity by about 250 mAhg(-1) in each cycle (after activation) for Mg-Ni-La electrodes with 0.2 G/A nanocomposites.