• 文献标题:   Facilitation of Water Penetration through Zero-Dimensional Gates on Rolled-up Graphene by Cluster-Chain-Cluster Transformations
  • 文献类型:   Article
  • 作  者:   OHBA T, KANOH H, KANEKO K
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Chiba Univ
  • 被引频次:   7
  • DOI:   10.1021/jp302769m
  • 出版年:   2012

▎ 摘  要

We demonstrate a water penetration mechanism through zero-dimensional nanogates of a single-walled carbon nanohorn. Water vapor adsorption via the nanogates is delayed in the initial adsorption stage but then proceeds at a certain rate. The mechanism is proposed to be a water cluster-chain-cluster transformation via the nanogates. The growth of water clusters in internal nanospaces facilitates water penetration into these nanospaces, providing an intrinsic mechanism for zero-dimensional water.