• 文献标题:   Comparing the electrophoretic deposition process of graphene oxides synthesized through different methods
  • 文献类型:   Article
  • 作  者:   HOSSEINPOUR A, ABDIZADEH H, GOLOBOSTANFARD MR
  • 作者关键词:   graphene oxide, chemical synthesis method, electrophoretic deposition, thin film
  • 出版物名称:   THIN SOLID FILMS
  • ISSN:   0040-6090
  • 通讯作者地址:   Univ Tehran
  • 被引频次:   7
  • DOI:   10.1016/j.tsf.2017.04.013
  • 出版年:   2017

▎ 摘  要

Graphene oxide (GO) is synthesized through two different chemical methods, namely modified improved method (MIM) and modified Hummers method (MHM). Electrophoretic deposition of GO obtained from those methods is performed on the Fluorine doped tin oxide glass substrates by dispersing GO sheets in acetonitrile and applying voltage. UV-vis and Raman spectroscopies show that pristine graphite is less oxidized in the MIM. However, X-ray diffraction patterns indicate that d-spacing of GO sheets is more increased in the MIM (d-spacing of 0.94 nm vs. 0.77 nm). Also, Fourier-transformed infrared spectroscopy reveals that GO synthesized through the MIM contains more C=O functional groups on its surface. As a result, current density-time diagrams and field emission scanning electron microscope (FESEM) cross-sectional images of electrophoretically deposited GO films are indicative of higher average deposition rate in the MIM compared to MHM (similar to 5.1 nm/s vs. similar to 1.8 nm/s). FESEM images of the two films show that surface roughness of the MIM film is lower than that of MHM film as well. (C) 2017 Elsevier B.V. All rights reserved.