▎ 摘　　要

A free-standing paper-like three-dimensional graphene framework (3DGF) with orientated laminar structure and interconnected macropores, was obtained by the hard template-directed ordered assembly. As the sacrificial templates, polystyrene (PS) latex spheres were assembled with graphene oxide (GO) to build up a sandwich type composite film, followed by heat removal of which with a simultaneous reduction of GO. The 3DGF exhibited high specific surface area of 402.5 m(2)/g, controllable pores and mechanical flexibility, which was employed as the binder-free supercapacitor electrode and shows high specific gravimetric capacitance of 95 Fig at 0.5 A/g, with enhanced rate capability in 3 electrode KOH system. (C) 2015 Science Press and Dalian Institute of Chemical Physics. All rights reserved.