• 文献标题:   Electrodepositing manganese oxide into a graphene hydrogel to fabricate an asymmetric supercapacitor
  • 文献类型:   Article
  • 作  者:   CHI HZ, WU YQ, SHEN YK, ZHANG CX, XIONG QQ, QIN HY
  • 作者关键词:   graphene hydrogel, manganese oxide, electrodeposition, asymmetric supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Hangzhou Dianzi Univ
  • 被引频次:   12
  • DOI:   10.1016/j.electacta.2018.09.025
  • 出版年:   2018

▎ 摘  要

Asymmetric supercapacitors possess advantages of elevated capacitance, extended output voltage, and then improved power-energy characteristic. Here we report on a composite electrode prepared by electrodepositing manganese oxide into a graphene hydrogel and its capacitive performance in an asymmetric supercapacitor. The manganese oxide/graphene hydrogel exhibits a specific capacitance of 352.9 F g(-1) at 1 A g(-1). The aqueous asymmetric supercapacitor composed of an active carbon as a negative electrode and the manganese oxide/graphene hydrogel as a positive electrode possesses good cycle stability (91.5% of capacitance retention after 5000 cycles) and is able to deliver an energy density of 41.8 Wh kg(-1) at a power density of 0.2 kW kg(-1). Its possibility to serve as a power supply for a practical application was verified by lighting up a blue light-emitting diode. These results demonstrate the electrodeposition process has promising prospect in the preparation of high-performance composite electrodes for advanced electrochemical energy storage devices. (C) 2018 Elsevier Ltd. All rights reserved.