• 文献标题:   Heterogenization of amine-functionalized ionic liquids using graphene oxide as a support material: a highly efficient catalyst for the synthesis of 3-substituted indoles via Yonemitsu-type reaction
  • 文献类型:   Article
  • 作  者:   GARKOTI C, SHABIR J, GUPTA P, SHARMA M, MOZUMDAR S
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Univ Delhi
  • 被引频次:   5
  • DOI:   10.1039/c7nj03450d
  • 出版年:   2017

▎ 摘  要

In the present study, heterogenization of amine-functionalized ionic liquids was developed via covalent immobilization of 2-chloroethylamine on imidazole modified graphene oxide (GO) sheets. The prepared material was characterized by various physicochemical techniques such as Fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (XRD), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) spectroscopy. The prepared material was employed as an efficient heterogeneous catalyst for the synthesis of 3-substituted indoles via Yonemitsu-type reaction. The catalyst could be easily separated from the reaction mixture through centrifugation and could be reused for seven consecutive cycles without any appreciable loss in its catalytic activity.