• 文献标题:   Molecularly imprinted polymer containing fluorescent graphene quantum dots as a new fluorescent nanosensor for detection of methamphetamine
  • 文献类型:   Article
  • 作  者:   MASTERIFARAHANI M, MASHHADIRAMEZANI S, MOSLEH N
  • 作者关键词:   graphene quantum dot, molecularly imprinted polymer, nanosensor, methamphetamine, fluorescence
  • 出版物名称:   SPECTROCHIMICA ACTA PART AMOLECULAR BIOMOLECULAR SPECTROSCOPY
  • ISSN:   1386-1425 EI 1873-3557
  • 通讯作者地址:   Kharazmi Univ
  • 被引频次:   4
  • DOI:   10.1016/j.saa.2019.118021
  • 出版年:   2020

▎ 摘  要

A novel fluorescent nanosensor based on graphene quantum dots embedded within molecularly imprinted polymer (GQDs@MIP) was developed for detection and determination of methamphetamine (METH). The resulting GQDs@MIP nanocomposite exhibited higher methamphetamine selectivity in comparison with corresponding non-imprinted polymer (GQDs@NIP). Characterization of the GQDs@MIP nanocomposite was done by nitrogen adsorption and desorption analysis (BET method), transmission electron microscopy (TEM), photoluminescence (PL), ultraviolet-visible (UV-Vis), and Fourier transform infrared (FT-IR) spectroscopies. The fluorescence intensity of GQDs@MIP was efficiently quenched in the presence of methamphetamine template molecules while no quenching was observed in the presence of other analytes such as amphetamine, ibuprofen, codeine, and morphine. Using this method, the detection limit of 1.7 mu g/L was obtained for methamphetamine determination. (c) 2018 Elsevier B.V. All rights reserved.