• 文献标题:   Electrocatalytic Activity of Immobilized Co(II) on Porous Graphene Aerogels
  • 文献类型:   Article
  • 作  者:   BAGHERI S, RAMIMOGHADAM D, MANSOURI N, ABD HAMID SB
  • 作者关键词:   graphene aerogel, electrocatalyst, co ii ion, oxygen evolution reaction, electrolysi
  • 出版物名称:   JOURNAL OF THE CHINESE CHEMICAL SOCIETY
  • ISSN:   0009-4536 EI 2192-6549
  • 通讯作者地址:   Univ Malaya
  • 被引频次:   3
  • DOI:   10.1002/jccs.201500350
  • 出版年:   2016

▎ 摘  要

The highly-porous graphene aerogel (GA) with BET surface area of 810 m(2) g(-1) and three-dimensional structure has been successfully fabricated using the hydrothermal technique. The modified glassy carbon electrode was then prepared by casting the graphene aerogel solution followed by immersing the GA/GCE in Co+2 solution. The results showed that graphene aerogels improved the adsorption ability of the Co (II) ions. The electrocatalysis of oxygen evolution reaction (OER) at the Co-GA modified glassy carbon electrode (Co-GA/GCE) has been investigated using linear sweep voltammetry (LSV) in alkaline solution. The OER was noticeably enhanced at Co-GA/GCE, representing a negative shift in the LSV curve at the Co-GA/GCE compared to that obtained at the bare GCE. The high electrocatalytic activity, good reproducibility and low cost of proposed electrode provides desired characteristics of a potential candidate in the industrial water electrolysis process.