• 文献标题:   Quenching of fluorescence of aromatic molecules by graphene due to electron transfer
  • 文献类型:   Article
  • 作  者:   MATTE HSSR, SUBRAHMANYAM KS, RAO KV, GEORGE SJ, RAO CNR
  • 作者关键词:  
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   Jawaharlal Nehru Ctr Adv Sci Res
  • 被引频次:   97
  • DOI:   10.1016/j.cplett.2011.03.031
  • 出版年:   2011

▎ 摘  要

Investigations on the fluorescence quenching of graphene have been carried out with two organic donor molecules, pyrene butanaoic acid succinimidyl ester (PyBS, I) and oligo(p-phenylenevinylene) methyl ester (OPV-ester, II). Absorption and photoluminescence spectra of I and II recorded in mixture with increasing the concentrations of graphene showed no change in the former, but remarkable quenching of fluorescence. The property of graphene to quench fluorescence of these aromatic molecules is shown to be associated with photo-induced electron transfer, on the basis of fluorescence decay and time-resolved transient absorption spectroscopic measurements. (C) 2011 Elsevier B. V. All rights reserved.