• 文献标题:   On the behavior of reduced graphene oxide based electrodes coated with dispersed platinum by alternate current methods in the electrochemical degradation of reactive dyes
  • 文献类型:   Article
  • 作  者:   DEL RIO AI, GARCIA C, MOLINA J, FERNANDEZ J, BONASTRE J, CASES F
  • 作者关键词:   reduced graphene oxide, dispersed platinum, alternate current method, reactive dye, electrochemical treatment
  • 出版物名称:   CHEMOSPHERE
  • ISSN:   0045-6535 EI 1879-1298
  • 通讯作者地址:   Univ Politecn Valencia
  • 被引频次:   2
  • DOI:   10.1016/j.chemosphere.2017.05.121
  • 出版年:   2017

▎ 摘  要

The electrochemical behavior of different carbon-based electrodes with and without nanoparticles of platinum electrochemically dispersed on their surface has been studied. Among others, reduced graphene oxide based electrodes was used to determine the best conditions for the decolorization/degradation of the reactive dye C.I. Reactive Orange 4 in sulfuric medium. Firstly, the electrochemical behavior was evaluated by cyclic voltammetry. Secondly, different electrolyses were performed using two cell configurations: cell with anodic and cathodic compartments separated (divided configuration) and without any separation (undivided configuration). The best results were obtained when reduced graphene oxide based anodes were used. The degree of decolorization was monitored by spectroscopic methods and high performance liquid chromatography. It was found that all of them followed pseudo first order kinetics. When reduced graphene oxide-based electrodes coated with dispersed platinum by alternate current methods electrodes were used, the lowest energy consumption and the higher decolorization kinetics rate were obtained. Scanning Electronic Microscopy was used to observe the morphological surface differences. (C) 2017 Elsevier Ltd. All rights reserved.