• 文献标题:   Electrochemical Enantiomer Recognition Based on sp(3)-to-sp(2) Converted Regenerative Graphene/Diamond Electrode
  • 文献类型:   Article
  • 作  者:   GAO JY, ZHANG HY, YE C, YUAN QL, CHEE KWA, SU WT, YU AM, YU JH, LIN CT, DAI D, FU L
  • 作者关键词:   graphene, chemical vapor deposition, electronic material, enantiomer recognition, phenylalanine
  • 出版物名称:   NANOMATERIALS
  • ISSN:   2079-4991
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   4
  • DOI:   10.3390/nano8121050
  • 出版年:   2018

▎ 摘  要

It is of great significance to distinguish enantiomers due to their different, even completely opposite biological, physiological and pharmacological activities compared to those with different stereochemistry. A sp(3)-to-sp(2) converted highly stable and regenerative graphene/diamond electrode (G/D) was proposed as an enantiomer recognition platform after a simple beta-cyclodextrin (beta-CD) drop casting process. The proposed enantiomer recognition sensor has been successfully used for D and L-phenylalanine recognition. In addition, the G/D electrode can be simply regenerated by half-minute sonication due to the strong interfacial bonding between graphene and diamond. Therefore, the proposed G/D electrode showed significant potential as a reusable sensing platform for enantiomer recognition.