• 文献标题:   Highly-flexible and -stable deep-ultraviolet photodiodes made of graphene quantum dots sandwiched between graphene layers
  • 文献类型:   Article
  • 作  者:   JANG CW, SHIN DH, CHOI SH
  • 作者关键词:   graphene quantum dot, graphene, photodiode, flexible, deepultraviolet
  • 出版物名称:   DYES PIGMENTS
  • ISSN:   0143-7208 EI 1873-3743
  • 通讯作者地址:   Kyung Hee Univ
  • 被引频次:   9
  • DOI:   10.1016/j.dyepig.2018.12.005
  • 出版年:   2019

▎ 摘  要

We first report highly-flexible and -stable deep-ultraviolet (DUV) photodiodes (PDs) by employing graphene (GR) quantum dots (GQDs) sandwiched between top/bottom GR layers on polyethylene terephthalates (PETs). Here, 3-aminopropyl triethoxysilane is inserted between the bottom GR and the PET substrate to enhance the bending stabilities without degradation or delamination by the chemical bonding. GQDs of similar to 5 nm diameter are proved to be well formed on the bottom GR by various structural and optical analysis tools including high-resolution transmission electron microscopy, Raman scattering, and photoluminescence. The DUV PDs exhibit 10 photo-/dark-current ratio, 0.1 AW(-1) responsivity (R), and 1.1 x 10(13) cm Hz(1/2)/W detectivity at a wavelength of 254 nm. In addition, the R is reduced by only 13% even after 1000-times repeated bending tests at a bending curvature of 4 mm, and is almost consistent during the operations for 1000 h under ambient conditions.