• 文献标题:   Non-Covalent Functionalization of Graphene with Bisphenol A for High-Performance Supercapacitors
  • 文献类型:   Article
  • 作  者:   HU HX, HU ZG, REN XY, YANG YY, QIANG RB, AN N, WU HY
  • 作者关键词:   noncovalent functionalization, electrochemical propertie, stacking interaction, supercapacitor
  • 出版物名称:   CHINESE JOURNAL OF CHEMISTRY
  • ISSN:   1001-604X EI 1614-7065
  • 通讯作者地址:   Northwest Normal Univ
  • 被引频次:   32
  • DOI:   10.1002/cjoc.201400740
  • 出版年:   2015

▎ 摘  要

The reduced graphene oxide (RGO)/bisphenol A (BPA) composites were prepared by an adsorption-reduction method. The composites are characterized by X-ray diffraction (XRD), UV-vis, thermogravimetric (TG) analysis, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM). The results confirm that BPA is adsorbed on the basal plane of RGO by Pi-Pi stacking interaction. Furthermore, the electrochemical behaviors were evaluated by cyclic voltammetry, galvanostatic charge/discharge techniques and electrochemical impedance spectroscopy (EIS). The results show that the RGO/BPA nanocomposites exhibit ultrahigh specific capacitance of 466 F center dot g(-1) at a current density of 1 A center dot g(-1), excellent rate capability (more than 81% retention at 10 A center dot g(-1) relative to 1 A center dot g(-1)) and superior cycling stability (90% capacitance decay after 4000 cycles). Consequently, the RGO/BPA nanocomposites can be regarded as promising electrode materials for supercapacitor applications.