• 文献标题:   A simple route to improve rate performance of LiFePO4/reduced graphene oxide composite cathode by adding Mg2+ via mechanical mixing
  • 文献类型:   Article
  • 作  者:   HUANG Y, LIU H, GONG L, HOU YL, LI Q
  • 作者关键词:   mg2+, reduced graphene oxide, lifepo4, liion battery, rate performance
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Chinese Univ Hong Kong
  • 被引频次:   16
  • DOI:   10.1016/j.jpowsour.2017.02.043
  • 出版年:   2017

▎ 摘  要

Introducing Mg2+ to LiFePO4 and reduced graphene oxide composite via mechanical mixing and annealing leads to largely improved rate performance of the cathode (e.g. similar to 78 mA h g(-1) at 20 C for LiFePO4 and reduced graphene oxide composite with Mg2+ introduction vs. similar to 37 mA h g(-1) at 20 C for LiFePO4 and reduced graphene oxide composite). X-ray photoelectron spectroscopy unravels that the enhanced reduction of Fe2+ to Fe-0 occurs in the simultaneous presence of Mg2+ and reduced graphene oxide, which is beneficial for the rate capability of cathode. The simple fabrication process provides a simple and effective means to improve the rate performance of the LiFePO4 and reduced graphene oxide composite cathode.(C) 2017 Elsevier B.V. All rights reserved.