• 文献标题:   Oil-water interfacial synthesis of graphene-polyaniline-MnO2 hybrids using binary oxidant for high performance supercapacitor
  • 文献类型:   Article
  • 作  者:   LI KJ, GUO DF, CHEN JM, KONG Y, XUE HG
  • 作者关键词:   polyaniline, graphene, mno2, interfacial synthesi, binary oxidant, supercapacitor
  • 出版物名称:   SYNTHETIC METALS
  • ISSN:   0379-6779
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   21
  • DOI:   10.1016/j.synthmet.2015.09.017
  • 出版年:   2015

▎ 摘  要

Graphene-polyaniline-MnO2 (G-P-Mn) hybrids were synthesized via a facile approach that includes the reduction of graphene oxide (GO) to graphene (G) by aniline and then followed by oil-water interfacial polymerization of aniline to polyaniline (PANI) using a binary oxidant of KMnO4 and (NH4)S2O8. PANT was orderly nanofibered and MnO2-doped due to interfacial polymerization and the use of binary oxidant. The hybrids conclude electrical double layer capacitance of G and pseudo capacitance of PANI and MnO2, showing enhanced specific capacitance of 800.1 F g(-1) at 0.4A g(-1) with good cycling stability. (C) 2015 Elsevier B.V. All rights reserved.