• 文献标题:   Flower-like SnO2 nanoparticles grown on graphene as anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   GUO Q, QIN X
  • 作者关键词:   sno2, graphene, composite, anode material, lithiumion batterie
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   24
  • DOI:   10.1007/s10008-013-2352-4
  • 出版年:   2014

▎ 摘  要

Tin oxide (SnO2)/graphene composite was synthesized from SnCl2 center dot 2H(2)O and graphene oxide (GO) by a wet chemical-hydrothermal route. The GO was reduced to graphene nanosheet (GNS) and flower-like SnO2 nano-crystals with size about 40 nm were homogeneously distributed on the surface of GNS. The SnO2/graphene composites delivered a superior first discharge capacity of 1941.9 mAhg(-1) with a reversible capacity of 901.7 mAhg(-1) at the current density of 100 mAg(-1). Moreover, even at higher densities of 200 and 500 mAg(-1), the SnO2/graphene composite still maintained enhanced cycling stability. After 40 cycles, the discharge capacity was still maintained at 691.1 mAhg(-1) at the current density of 100 mAg(-1). The SnO2/graphene composite displayed an outstanding Li-battery performance with large reversible capacity and enhanced rate performance, which can be attributed to the highly uniform distribution of SnO2 nanoparticles and high reduction degree of graphene. This result strongly indicates that the SnO2/graphene composite was a promising anode material in high-performance lithium-ion batteries.