• 文献标题:   Effect of synthesis conditions on the properties of graphene doped with nitrogen atoms
  • 文献类型:   Article
  • 作  者:   CHESNOKOV VV, CHICHKAN AS, GERASIMOV EY
  • 作者关键词:   graphene, magnesium oxide, ethylene, acetylene, ammonia, carbonization
  • 出版物名称:   FULLERENES NANOTUBES CARBON NANOSTRUCTURES
  • ISSN:   1536-383X EI 1536-4046
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1080/1536383X.2021.1994553 EA OCT 2021
  • 出版年:   2022

▎ 摘  要

Graphene doped with nitrogen atoms (N-graphene) was prepared by the template method. Magnesium oxide was subjected to carbonization in the 40% NH3-1% C2H2-C2H4 mixture at 650-750 degrees C. Then, the MgO core of the prepared N-C/MgO composite was dissolved by treatment in hydrochloric acid. The effects of temperature and synthesis time on the properties of the obtained N-graphene were studied by electron microscopy, Raman spectroscopy, XPS and XRD. The aggregates consisted of N-graphene particles with globular shape reflecting the template method used for their synthesis. The size of the carbon globules was about 30-50 nm. According to the chemical mapping data, C, O and N atoms were uniformly distributed in N-graphene within the analysis area. An increase of the synthesis temperature from 650 to 750 degrees C led to the decrease of the sample defectiveness, nitrogen atom concentration and surface area of N-graphene.