• 文献标题:   UV-assisted one-pot synthesis of bimetallic Ag-Pt decorated reduced graphene oxide for colorimetric determination of hydrogen peroxide
  • 文献类型:   Article
  • 作  者:   YAO L, KONG FY, WANG ZX, LI HY, ZHANG R, FANG HL, WANG W
  • 作者关键词:   bimetallic nanoparticle, nanocomposite, ultraviolet irradiation method, nanozyme, peroxidaselike activity, 3, 3, 5, 5tetramethylbenzidine, colorimetric method, spectrophotometry, hydrogen peroxide
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Yancheng Inst Technol
  • 被引频次:   0
  • DOI:   10.1007/s00604-020-04350-3
  • 出版年:   2020

▎ 摘  要

Bimetallic Ag-Pt nanoparticles decorated on the surface of reduced graphene oxide (Ag-Pt/rGO) were designed and selected as a nanozyme for the assay of hydrogen peroxide. The nanocomposites were prepared through a one-pot reduction of potassium chloroplatinate, silver nitrate, and graphene oxide under ultraviolet irradiation without using any extra chemical reducing agents or surfactants. The successful formation of Ag-Pt/rGO nanocomposites was confirmed by transmission electron microscopy, energy disperse spectroscopy mapping, X-ray photoelectron spectroscopy, and X-ray diffraction analysis. Significantly, Ag-Pt/rGO nanocomposites possessed excellent peroxidase-like activity toward the catalytic oxidation of 3,3,5,5-tetramethylbenzidine to form a blue product in the presence of hydrogen peroxide. Steady-state kinetics studies suggested that Ag-Pt/rGO nanocomposites had high affinity to hydrogen peroxide. Based on these properties, a convenient and sensitive method for the colorimetric determination of hydrogen peroxide was developed. Under optimal conditions, the absorbance at 652 nm increases linearly in the 10-100 mu M and 100 mu M-1 mM ranges of hydrogen peroxide concentration, and the detection limit is 0.9 mu M (S/N=3). The method was successfully applied to the determination of hydrogen peroxide in real water samples.p id="Par