• 文献标题:   Electrochemical Determination of Rutin Using SnO2/nitrogen-doped Graphene Composite Electrode
  • 文献类型:   Article
  • 作  者:   PENG YQ, LIAO MX, MA X, DENG H, GAO F, DAI RY, LU LM
  • 作者关键词:   sno2 nanoparticle, nitrogendoped graphene, rutin, electrochemical determination
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Jiangxi Agr Univ
  • 被引频次:   2
  • DOI:   10.20964/2019.06.28
  • 出版年:   2019

▎ 摘  要

Herein, the nanocomposites of SnO2 nanoparticles on the nitrogen-doped graphene (SnO2/NG) as a sensitive electrochemical sensing platform for rutin determination were easily prepared via a facile hydrothermal method. The results showed that the existence of NG in SnO2/NG composites could dramatically improve the conductivity, facilitate the electron transfer and enhance the electro-catalytic activity of rutin. Compared with pure SnO2, NG and SnO2/graphene, the as-prepared SnO2/NG nanocomposite presented improved electrocatalytic activity for the oxidation of rutin due to the synergetic effects from SnO2 and NG. Combined with differential pulse voltammetry, the prepared sensor based on SnO2/NG modified electrode displayed a wide linear range from 0.4 nM to 2 mu M with a detection limit of 0.2 nM. The modified electrode exhibited high stability and reproducibility as well as good selectivity. These results suggest that SnO2/NG could be successfully applied for detecting rutin in practical samples.