• 文献标题:   A highly-sensitive sensor based on carbon nanohorns@reduced graphene oxide coated by gold platinum core-shell nanoparticles for electrochemical detection of carbendazim in fruit and vegetable juice
  • 文献类型:   Article
  • 作  者:   LI WZ, WANG PX, CHU BB, CHEN XG, PENG ZC, CHU JY, LIN R, GU QH, LU J, WU DH
  • 作者关键词:   carbendazim, electrochemical sensor, carbon nanohorn, reduced graphene oxide, gold platinum coreshell nanoparticle, pesticide residue
  • 出版物名称:   FOOD CHEMISTRY
  • ISSN:   0308-8146 EI 1873-7072
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/.foodchem.2022.134197
  • 出版年:   2023

▎ 摘  要

Carbendazim (CBZ) is beneficial to fruit and vegetable cultivation, but its residue will cause fruit and vegetable juice pollution. In this work, an electrochemical sensor based on carbon nanohorns@reduced graphene oxide coated by gold platinum core-shell nanoparticles (Au@Pt/CNHs@RGO/GCE) was prepared for CBZ detection. The results showed that the assembly of CNHs and RGO assisted by ultrasound improved the electron transfer ability and electrochemical active surface area of CNHs@RGO. Moreover, the coating of Au@Pt nanoparticles further enhanced the sensitivity of the sensor. With the synergistic effect of the three materials, the sensor had a wider linear range (0.05 mu mol/L-50 mu mol/L), a lower limit of detection (1.64 nmol/L), and satisfactory recovery rates (90.60 % similar to 97.60 %, carrot juice; 94.00-114.43 %, orange juice). Additionally, the sensor presented good anti-interference and repeatability. This work provides a simple, rapid, economical, sensitive, and accurate sensor for CBZ quantification in fruit and vegetable juice.