• 文献标题:   Self-assembled lithium manganese oxide nanoparticles on carbon nanotube or graphene as high-performance cathode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHAO X, HAYNER CM, KUNG HH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Northwestern Univ
  • 被引频次:   44
  • DOI:   10.1039/c1jm12373d
  • 出版年:   2011

▎ 摘  要

LiMn2O4-carbon composites composed of similar to 7 nm LiMn2O4 nanoparticles homogeneously anchored on conducting carbon nanotubes and graphene nanosheets were fabricated via a self-assembly process combined with solid-state lithiation. Owing to improved Li diffusion kinetics achieved by the small particle size and intimate electrical contact with a porous, conducting carbon matrix, reversible capacities close to the theoretical value with enhanced power capability and cyclability were attained for these highly crystalline LiMn2O4-carbon composite cathodes. The facile self-assembly approach can be readily adapted to different carbon supports and could serve as a general synthetic strategy towards controlled fabrication of other functional hybrids for high-performance energy storage devices.