• 文献标题:   Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   GUO P, SONG HH, CHEN XH
  • 作者关键词:   lithiumion batterie, graphene nanosheet, graphite, cycle performance, ac impedance
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   461
  • DOI:   10.1016/j.elecom.2009.04.036
  • 出版年:   2009

▎ 摘  要

Graphene nanosheets (GNSs) were prepared from artificial graphite by oxidation, rapid expansion and ultrasonic treatment. The morphology, structure and electrochemical performance of GNSs as anode material for lithium-ion batteries were systematically investigated by high-resolution transmission electron microscope, scanning electron microscope, X-ray diffraction, Fourier transform infrared spectroscopy and a variety of electrochemical testing techniques. It was found that GNSs exhibited a relatively high reversible capacity of 672 mA h/g and fine cycle performance. The exchange current density of GNSs increased with the growth of cycle numbers exhibiting the peculiar electrochemical performance. (C) 2009 Elsevier B.V. All rights reserved.