• 文献标题:   High-performance anode materials based on 3D orderly and vertically macroporous graphene-Si framework for Li-ion batteries
  • 文献类型:   Article
  • 作  者:   MIAO FJ, CONG WJ, MIAO R, WANG N, WU WY, ZANG Y, SHI CP, ZHU L, TAO BR, CHU PK
  • 作者关键词:   graphene/simcp, anode, liion batterie, electrochemical exfoliation
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Qiqihar Univ
  • 被引频次:   1
  • DOI:   10.1007/s11581-018-2653-9
  • 出版年:   2019

▎ 摘  要

Porous graphene/Si-MCP (microchannel plate) microstructures are fabricated using electrochemical exfoliation and microelectronic machining. The few-layer graphene nanosheets with a lateral size of 600-850nm and thickness of 2-3nm are uniformed anchored on the surface and channels of the Si-MCP substrate. The as-prepared graphene/Si-MCP is used as the anode in lithium ion batteries and demonstrated to have a higher reversible capacity, better cycling retention, and excellent higher rate cycling performance compared to graphene/Si and Si-MCP. The good properties are attributed to the large surface-to-volume ratio of the structure and the better electrical contact with graphene. This silicon-based composite has large potential as anodes in integrated batteries.