• 文献标题:   Microwave preparation of triethylenetetramine modified graphene oxide/chitosan composite for adsorption of Cr(VI)
  • 文献类型:   Article
  • 作  者:   GE HC, MA ZW
  • 作者关键词:   graphene oxide, modified chitosan, microwave, adsorption, cr vi
  • 出版物名称:   CARBOHYDRATE POLYMERS
  • ISSN:   0144-8617 EI 1879-1344
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   78
  • DOI:   10.1016/j.carbpol.2015.06.025
  • 出版年:   2015

▎ 摘  要

A novel triethylenetetramine modified graphene oxide/chitosan composite (TGOCS) was successfully synthesized by microwave irradiation (MW) method and compared with one prepared by conventional heating. This composite was characterized by FUR, XRD, SEM, BET and elemental analysis. Adsorption of Cr(VI) on the composite was studied. The experimental results indicated that the product obtained by MW had higher yield and uptake than one obtained by the conventional and uptake of TGOCS for Cr(VI) was higher than that of the recently reported adsorbents. The effects of various variables on adsorption of Cr(VI) by TGOCS were further researched. The highest adsorption capacity of 219.5 mg g(-1) was obtained at pH 2. Adsorption followed pseudo-second-order kinetic model and Langmuir isotherm. The capacity increased as increasing temperature. The adsorbent could be recyclable. These results have important implications for the application expansion of microwave preparation and the design of new effective composites for Cr(VI) removal in effluents. (C) 2015 Elsevier Ltd. All rights reserved.