• 文献标题:   Ion-assisted construction of Sb/N-doped graphene as an anode for Li/Na ion batteries
  • 文献类型:   Article
  • 作  者:   NING XM, ZHOU XS, LUO J, MA L, ZHAN L
  • 作者关键词:   sb, 7 7 8 8tetracyanoquinodimethane, graphene, lithium ion batterie, sodium ion batterie
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Lingnan Normal Univ
  • 被引频次:   1
  • DOI:   10.1088/1361-6528/ab57a5
  • 出版年:   2020

▎ 摘  要

Although secondary batteries are common in many fields, new electrode materials with a reasonable structure are desired for high battery performance. Herein, Sb/N-doped graphene nanosheets (NGNS-Q) were constructed with the help of 7,7,8,8-tetracyanoquinodimethane anions (TCNQ center dot(-)). TCNQ center dot(-) were used to anchor Sb3+ into the graphene layer by electrostatic interaction, which improves the distribution of Sb nanoparticles. Meanwhile, TCNQ center dot(-) act as a N source to form N-doped graphene, enhancing the electron conductivity of the composite. Benefiting from the stable structure and good conductivity, the Sb/NGNS-Q composite achieved good electrochemical battery performance for Li/Na ion batteries (LIBs/SIBs). At a current density of 0.1 A g(-1), Sb/NGNS-Q exhibited a capacity of 615 mAh g(-1) after cycling 200 times and 240 mAh g(-1) after 100 cycles for LIBs and SIBs, respectively.