• 文献标题:   One-step facile hydrothermal synthesis of heteroatom-doped porous graphene reduced comparatively by different reductants for high performance supercapacitors
  • 文献类型:   Article
  • 作  者:   LI R, LAI LQ, SU SY, DAI HM, CUI YF, ZHU XH
  • 作者关键词:   graphene, heteroatom, porou, , hydrothermal, method, electrochemical propertie
  • 出版物名称:   MATERIALS TODAY COMMUNICATIONS
  • ISSN:   2352-4928
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   0
  • DOI:   10.1016/j.mtcomm.2020.101128
  • 出版年:   2020

▎ 摘  要

Taking advantage of hydrothermal methods to reduce graphene oxide (GO) is a convenient way and different heteroatoms on graphene or reduced graphene oxide (RGO) are vitally significant to its performance for application in supercapacitors. Accordingly, our work here is to implement a facile one-step hydrothermal reduction approach to obtain diversely doped graphene using various reductants of HI, Na2S2O3, NaBH4, N2H4 center dot H2O, CS(NH2)(2), by which I-doped, S-doped, B-doped, N-doped, and N, S dual-doped RGOs (represented as I-RGO, S-RGO, B-RGO, N-RGO, N/S-RGO, respectively) were fabricated. Through electrochemical characterization, it is presented that their electrochemical capacitance properties are ranked approximately in the order of N/S-RGO > N-RGO > S-RGO >= B-RGO > I-RGO, whereas I-RGO is in possession of a wider potential window than the others. Further structural and chemical analyses indicate that the O content within the RGOs is a primary effect on their performance, followed by the assistances from disparate heteroatom dopants existed in the RGOs and the porous construction inside graphene. As a result, a high specific capacitance of 263.3 F g(-1) is obtained in N/S-RGO at the current density of 1 A g(-1).