• 文献标题:   Transfer-free synthesis of graphene-like atomically thin carbon films on SiC by ion beam mixing technique
  • 文献类型:   Article
  • 作  者:   ZHANG R, CHEN FH, WANG JB, FU DJ
  • 作者关键词:   graphene, sic, ion beam mixing, carbon cluster ion
  • 出版物名称:   NUCLEAR INSTRUMENTS METHODS IN PHYSICS RESEARCH SECTION BBEAM INTERACTIONS WITH MATERIALS ATOMS
  • ISSN:   0168-583X EI 1872-9584
  • 通讯作者地址:   Taiyuan Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1016/j.nimb.2017.12.027
  • 出版年:   2018

▎ 摘  要

Here we demonstrate the synthesis of graphene directly on SiC substrates at 900 degrees C using ion beam mixing technique with energetic carbon cluster ions on Ni/SiC structures. The thickness of 7-8 nm Ni films was evaporated on the SiC substrates, followed by C cluster ion bombarding. Carbon cluster ions C-4 were bombarded at 16 keV with the dosage of 4 x 10(16) atoms/cm(2). After thermal annealing process Ni silicides were formed, whereas C atoms either from the decomposition of the SiC substrates or the implanted contributes to the graphene synthesis by segregating and precipitating process. The limited solubility of carbon atoms in silicides, involving SiC, Ni2Si, Ni5Si2, Ni3Si, resulted in diffusion and precipitation of carbon atoms to form graphene on top of Ni and the interface of Ni/SiC. The ion beam mixing technique provides an attractive production method of a transfer-free graphene growth on SiC and be compatible with current device fabrication.