• 文献标题:   Lanthanum cobaltite supported on graphene nanosheets for non-enzymatic electrochemical determination of catechol
  • 文献类型:   Article
  • 作  者:   SUVINA V, KOKULNATHAN T, WANG TJ, BALAKRISHNA RG
  • 作者关键词:   catechol, binary metal oxide, lanthanium cobaltite, electrocatalyst, environmental sample
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Jain Univ
  • 被引频次:   1
  • DOI:   10.1007/s00604-020-4165-3
  • 出版年:   2020

▎ 摘  要

An electrochemical sensor is described for the determination of catechol (CT) based on the nanocomposite of lanthanum cobaltite supported on graphene nanosheets (LaCo/GNS). The nanocomposite was systematically examined by various analytical and spectroscopic methods. The LaCo/GNS-modified electrode exhibites good electrochemical activity towards CT determination compared to other modified and unmodified electrodes. The electrochemical signal was acquired at a redox potential of 0.21 (E-pa) and 0.17 (E-pc) Volt (vs. Ag/AgCl). The proposed electrode exhibits low detection limit (1.0 nM), wide working range (0.009-132 mu M), and good sensitivity (5.68 mu A mu M-1 cm(-2)). The electrochemical nanoprobe has good selectivity over potentially interfering compounds. The electrochemical sensor was applied to the analysis of environmental samples with acceptable recovery. Schematic representation of electrochemical determination of catechol in the environmental sample analysis using lanthanum cobaltite supported on graphene nanosheets.