• 文献标题:   2-Mercaptobenzimidazole-inbuilt metal-organic-frameworks modified graphene oxide towards intelligent and excellent anti-corrosion coating
  • 文献类型:   Article
  • 作  者:   LI H, QIANG YJ, ZHAO WJ, ZHANG ST
  • 作者关键词:   2mercaptobenzimidazole, go, zif8, anticorrosion, selfhealing
  • 出版物名称:   CORROSION SCIENCE
  • ISSN:   0010-938X EI 1879-0496
  • 通讯作者地址:  
  • 被引频次:   103
  • DOI:   10.1016/j.corsci.2021.109715 EA JUL 2021
  • 出版年:   2021

▎ 摘  要

2-Mercaptobenzimidazole (M) was successfully inbuilt in zeolitic imidazolate framework-8 (ZIF-8) on GO nanosheets and then imbedded into epoxy coating to prepare composite coating with pH-responsive and self healing performances. Results showed that M-ZIF-8/GO possessed remarkable pH-triggered activity. The excellent self-healing behavior of M-ZIF-8/GO/EP coating was demonstrated by local electrochemical impedance spectroscopy, which was attributed to the release of corrosion inhibitors that could form a compact protective film on the metal. The anti-corrosion performance of matrix coating was also enhanced effectively because MZIF-8/GO could react with epoxy resin which greatly increased the compatibility of M-ZIF-8/GO and the crosslinking density of epoxy coating.