• 文献标题:   Nitrogen-doped Graphene Sheets Prepared from Different Graphene-Based Precursors as High Capacity Anode Materials for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   JIANG MH, CAI DD, TAN N
  • 作者关键词:   ndoped graphene, thermal annealing, different precursor, anode material, lithiumion batterie
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Guangxi Normal Univ
  • 被引频次:   4
  • DOI:   10.20964/2017.08.14
  • 出版年:   2017

▎ 摘  要

The nitrogen (N) doping in graphene-based materials has been considered as an effective approach to improve the lithium storage performance of lithium-ion batteries. Thus, the studies of the influence of N-doped graphene from different precursors on lithium storage properties are urgently needed. Herein, three different N-doped graphene sheets (N-GT, N-GN, N-RGN) anode materials of LIBs was prepared using the graphite oxides, graphene oxides and reduced graphene oxides as precursors respectively and thermal annealing with melamine. Microstructure tests show the N-RGN possess higher specific surface area (687.7 m(2) g(-1)), larger interlayer distance and more active sites due to the expanded graphene layers of reduced grapheme oxides than N-GT or N-GN. Electrochemical experiments results show that the order of lithium storage properties is N-RGN > N-GN > N-GT based on specific capacity and cycle performance, which can be explained for specific surface area of material as one of the key structural parameters. Moreover, a high initial reversible capacity of 1250.8 mAh g(-1) can be achieved for N-RGN at a current density of 100 mA g(-1).