• 文献标题:   Synthesis of Magnetite/Graphene Oxide Composite and Application for Cobalt(II) Removal
  • 文献类型:   Article
  • 作  者:   LIU MC, CHEN CL, HU J, WU XL, WANG XK
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   272
  • DOI:   10.1021/jp208575m
  • 出版年:   2011

▎ 摘  要

A magnetite/graphene oxide (M/GO) composite was synthesized via a chemical reaction with a magnetite particle size of 10-15 nm and was developed for the removal of heavy metal ions from aqueous solutions. The composite was characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The sorption of Co(II) on the M/GO composite was carried out under various conditions, that is, contact time, sorbent content, pH, ionic strength, foreign ions, and temperature. The sorption isotherms of Co(II) on the M/GO composite could be described well by the Langmuir model. The thermodynamic parameters (Delta H-0, Delta S-0, and Delta G(0)) calculated from the temperature-dependent isotherms indicated that the sorption reaction of Co(II) on the M/GO composite was an endothermic and spontaneous process. M/GO can be separated and recovered by magnetic separation. Results show that the magnetic M/GO composite is a promising sorbent material for the preconcentration and separation of heavy metal ions from aqueous solutions.