• 文献标题:   A glassy carbon electrode modified with nitrogen-doped reduced graphene oxide and melamine for ultra-sensitive voltammetric determination of bisphenol A
  • 文献类型:   Article
  • 作  者:   QIN JY, SHEN J, XU XY, YUAN Y, HE GY, CHEN HQ
  • 作者关键词:   carbonbased nanomaterial, interaction, supramolecular system, sensor, voltammetry, differential pulse voltammetry, real sample analysi, endocrine disruptor, trace bpa, electrochemical detection
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   3
  • DOI:   10.1007/s00604-018-2998-9
  • 出版年:   2018

▎ 摘  要

A composite was prepared at room temperature from nitrogen-doped reduced graphene oxide (N-rGO) and melamine via -interaction. An ultra-sensitive electrochemical sensor for the determination of trace levels of bisphenol A (BPA) was obtained by coating a glassy carbon electrode (GCE) with the composite. The structure and morphology of composite were characterized by FTIR, Raman, XRD, XPS, SEM and TEM. Because of the synergetic effects of N-rGO and melamine, the modified GCE displays considerably enhanced sensitivity to BPA. The voltammetric response, typically measured at a peak of 0.48V (vs. SCE) is linear in the 0.05 to 20M BPA concentration range, and the detection limit is 0.8nM (at S/N=3). The sensor is reproducible, stable and selective. It was applied to analyze baby bottles, drinking cups, mineral water bottles and shopping receipts that were spiked with BPA, and the recoveries reached 99.1-101.4%.